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The present historical-critical essay traces the peculiarities of classical phenomenological thermodynamics back to the paradigmatic framework created by CARNOT and takes up a few questions to which this paradigm gives rise. The results for the equilibrium thermodynamics and the second law are given and relevant objections are discussed. Several issues which are of interest for other approaches are presented. A broader question on the relation between some key concepts of thermodynamics is considered and discussed. Thermodynamics as a fundamental physical theory is advanced on the basis of some conclusions of the derivation. Although the results are not new, they are presented in a structured form, in which the role of the paradigm in the interpretation of thermodynamics is explicitly stated.
Abstract Traditionally, thermodynamics was considered to be a purely classical theory, and no relations to statistical mechanics were anticipated. CARNOT realized this assumption as being incomplete and presented a correct classical formulation of thermodynamics, which is based on the energy and entropy of a system. Its significance was not realized until recently. The present historic-critical essay traces the peculiarities of classical phenomenological thermodynamics back to the paradigm, created by CARNOT, and takes up some questions to which this paradigm gives rise. The results for the equilibrium thermodynamics and the second law are given and relevant objections are discussed. Several issues which are of interest for other approaches are presented. A broader question on the relation between some key concepts of thermodynamics is considered and discussed. Thermodynamics as a fundamental physical theory is advanced on the basis of some conclusions of the derivation. Although the results are not new, they are presented in a structured form, in which the role of the paradigm in the interpretation of thermodynamics is explicitly stated.
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